Tungsten Carbide: Synthesis, Structure, Properties, Applications

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The combination of tungsten metal with carbon atoms results in the material known as tungsten carbide. It is a chemical substance called WC, and its most basic form is a gray powder. It is an extremely hard substance that is frequently utilized in the manufacture of tools and wear-resistant components. It has an extremely high melting point and can resist extremely high temperatures. Tungsten carbide is also extremely corrosion resistant. Compared to other metals like gold, silver, or platinum, tungsten carbide is particularly durable.

Tungsten Carbide

Tungsten is a solid, light grey metal with a melting point of 3422 °C and excellent corrosion resistance. Its hardness (7.5 on the Mohs Scale) is equivalent to that of hardened steel or emerald, making it soft enough to be cut with a hacksaw. It’s also quite ductile and can be twisted into wire, which is why tungsten is used as a filament in most lightbulbs. It is also utilized in medical equipment and for specialized welding applications.

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Structure of Tungsten Carbide

Tungsten carbide structure

Synthesis of Tungsten Carbide

Tungsten carbide is made by heating tungsten metal and carbon to 1400°C – 2000°C. A lower-temperature fluid bed procedure that combines tungsten metal or blue WO3 with a CO/CO2 mixture and H2 between 900°C and 1200 °C is another method.

Another method of creating WC involves heating WO3 with graphite: either directly at 900 °C or in hydrogen at 670 °C, then carburization in argon at 1000 °C. The following chemical vapor deposition techniques have been researched:

Tungsten hexachloride is reacted with hydrogen (as a reducing agent) and methane (as a carbon source) at 670 °C (943 K).

WCl6 + H2 + CH4 → WC + 6 HCl

At 350 °C (623 K), tungsten hexafluoride is reacted with hydrogen (as a reducing agent) and methanol (as a carbon source).

WF6 + 2 H2 + CH3OH → WC + 6 HF + H2O

Physical Properties of Tungsten Carbide

Different grades of tungsten carbide have different strengths, rigidities, and other qualities, however all tungsten carbide material fits into the main categories described below.

Chemical Properties of Tungsten Carbide

Applications of Tungsten Carbide

Due to its distinct characteristics and remarkable attributes, tungsten carbide is a highly sought-after material for several applications. Tungsten has a wide range of uses and is valuable in a variety of industries than only manufacturing and industry. Examples include the medical sector, the fashion industry, and many more.

Construction

Construction requires the use of tools that are both powerful and durable in order to deal with the materials that most constructions are built of. It takes a very strong and resilient blade or drill bit, such those composed of tungsten carbide, to cut through tough materials like cement and asphalt. Due to its nearly indestructible nature, tungsten carbide is frequently used in construction products like drill bits and saws.

Ammunition

Tungsten carbide is widely employed in armor-piercing ammunition, either as a monolithic sintered type or as a tungsten carbide cobalt composite, especially when depleted uranium is unavailable or politically unpalatable. Tungsten carbide was only utilized to make machine tools and a small number of projectiles. It is an effective penetrator due to its great hardness and density.

Alloys

Alloys are made by combining metals with other metals or elements to produce electronics, building materials, industrial gears, and even aviation equipment. These alloys are created to have the particular characteristics, like as strength or heat resistance, required for each unique product and its usage. For building supplies and equipment, tungsten carbide alloys are a particularly well-liked option. These alloys are produced using around 17% of the total tungsten carbide utilized today.

Jewelry

A new and intriguing use for tungsten carbide is in the jewelry industry. Tungsten carbide jewelry may be as beautiful as any other item you might ordinarily wear if it is cut, produced, and polished properly. Tungsten carbide is a more affordable alternative for jewelry than the gold or silver we’re used to paying for and is also recognized for its remarkable and superior scratch resistance. Due to its durability, this metal is now ruling the market and is frequently used to make earrings, necklaces, and rings.

Surgical Instruments

Many of the prospective applications for tungsten carbide are still being found, and one of these new applications is in the medical arena. Tungsten carbide is frequently used to make surgical equipment because it improves performance and is corrosion-resistant. It increases the durability and strength of the surgical instruments. The surgical sector benefits from the features of tungsten carbide, such as its ability to be sharpened while preserving hardness.

Effects of Tungsten Carbide on Human and Environment

Frequently Asked Questions (FAQ)

What is tungsten carbide?

Tungsten carbide is a tungsten-carbon alloy formed by heating tungsten powder with carbon and hydrogen at temperatures ranging from 1,400 to 1,600°C (2,550 to 2,900°F). The resultant alloy is 2-3 times more rigid than steel and has compressive strength that exceeds all known melted, cast, and forged metals. It has a high degree of deformation resistance and maintains its stability in conditions that might be extremely hot or cold.

How strong is tungsten carbide?

Tungsten carbide is exceptionally hard, having a Mohs hardness of 9 to 9.5 and a Vickers number of roughly 2600. In comparison, the Mohs hardness of diamond is 10, with diamond having the greatest hardness standard.
While tungsten carbide is not as hard as diamond, it has other physical properties that are far superior than diamond. Its rigidity, for example, can be twice that of steel, with a Young’s modulus of around 530-700 GPa, which is likewise twice that of steel.

Is tungsten carbide magnetic?

Tungsten carbide is an alloy whose magnetic properties are determined by either the Cobalt or Nickel binder. Furthermore, cobalt significantly attracts a magnet, but nickel does not. Tungsten Carbide will not attract a magnet if the binder is nickel, but it will if the binder is cobalt.

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